Blitzo accidentally killed his mother by knocking over a guy holding a birthday cake with lit candles, which started the tent they were in on fire which spread to some fireworks and caused a huge explosion
We haven't seen her in any flashbacks, but Blitzo seems like he loved her very much, so she was likely a good mother
Moxxie's mother was murdered by his father, but she seemed to be a good mother because she interceded when his father tried to get him to murder someone when he wasn't even old enough yet to cut his own steak. She also would cut up his steak for him